The solubilities of ZnCl,in 2-methyl-1-butanol and 3-methyl-1-butanol systems were measured with equilibrium method,respectively.
用平衡法分別測定了氯化鋅在2-甲基-l-丁醇和3-甲基-1-丁醇中的溶解度,用靜態(tài)法分別測定了在100℃～140℃不同溫度下含飽和ZnCl2的2-甲基-1-丁醇和3-甲基-1-丁醇的飽和蒸汽壓,進一步運用擬二元法原理分別用Glapeyron方程和Antoine方程關聯(lián)試驗數(shù)據(jù)。
Kinetic resolution of(R,S)-2-methyl-1-butanol was completed by porcine pancreatic lipase-catalyzed transesterification with triacetin in a solvent-free system.
1前言(S)-2-甲基-1-丁醇在手性精細化學品及藥物合成中有重要的作用[1]。
Adding a little bit TBA in the reaction material was found to reduce the surface acidity of sulfonic group cation resin catalyst,improve the catalyst s adsorption selectivity on 2-methyl-1-butene,and keep the conversion rate of crude isopentene in isomerization reaction at a high level,and markedly improve the selectivity of 2-methyl-2-butene.
通過在反應原料中加入少量的叔丁醇,降低了磺酸基陽離子交換樹脂催化劑表面的酸性,提高了催化劑對2-甲基-1-丁烯的吸附選擇性,使粗異戊烯在異構化反應中的轉化率保持較高水平,顯著提高了2-甲基-2-丁烯的選擇性,成功地開發(fā)了一種粗異戊烯異構化反應的新工藝。
Study on Getting (S)-(-)-2-methyl-1-butanol Based on Fusel Oil Material;
以雜醇油為原料制備（S）-（-）-2-甲基-1-丁醇的研究
Simulation of the extractive distillation with azeotropic system of 2-methyl-1-butanol and 2-methyl-1-butyl acetate
乙酸2-甲基-1-丁酯與2-甲基-1-丁醇共沸體系萃取精餾分離的模擬
Study on Resolution of Racemic 2-methyl-1-butanol Catalyzed by Lipase;
脂肪酶催化拆分外消旋2-甲基-1-丁醇的研究
Study on Getting (S)-(-)-2-methyl-1-butanol Based on Fusel Oil Material;
以雜醇油為原料制備（S）-（-）-2-甲基-1-丁醇的研究
Study on the Catalytic Asymmetric Addition of 2-methyl-1-butene-3-yne to Aldehydes
2-甲基-1-丁烯-3-炔對醛的不對稱加成反應研究
Syntheses of 2-phenyl-1-butanol and 2-dimethylamino-2-phenylbutanenitrile
2-苯基-1-丁醇與2-二甲氨基-2-苯基丁腈的合成
MODIFIED SYNTHESIS OF 1-(6-METHOXY-2-NAPHTHYL)-BUTAN-1, 3-DIONE
1-(6-甲氧基-2-萘基)丁-1,3-二酮的工藝改進
Application of 1,3-Dichloro-5,5-Dimethylhydantoin for the Synthesis of 1-Chloro-2-Methyl-4-(Acetyloxy)-2-Butene
二氯海因在1-氯-2-甲基-4-乙酰氧基-2-丁烯制備中的應用
Synthesis and IR Spectra of the α{[(5-Fluoro-2,4-Dioxo-3,4-Dihydropyrimidin-1-(2H)-yl)Acetyl] Amino}-2-Methyl Butyric Acid
α-(5-氟尿嘧啶-1-基甲基甲?；?氨基-2-甲基丁酸的合成及紅外光譜研究
(2) Cis or trans 2,4 dimethylthietane;
(2 )順或反 2 ,4 -二甲基硫代環(huán)丁烷 ;
Synthesis of 1-Methoxy-2-methyl-Naphthalene
1-甲氧基-2-甲基萘的合成研究
Synthesis of 2-Isopropyl-2,3-dimethyl-butyric Acid
2,3-二甲基-2-異丙基-丁酸的合成
Study on Preparation and Chemical Structures of 1-methyl-3-butylimidazolium Chloride
氯化1-甲基-3-丁基咪唑的制備與表征
Technological Study of Synthesizing 2-Bromo-1-(6'-Methoxy-2'-Naphthalene) Propan-1-one;
2-溴-1-（6’-甲氧基-2’-萘基）丙-1-酮的合成工藝研究
2-amino-2-hydroxymethyl-1, 3-propanediol
2-氨基-2-羥甲-1, 3-丙二醇
Study on Synthesis of (R)-2-[(tert-Butyloxycarbonyl)amino]-3-methylene-methylbutyrate
(R)-2-氨基-3-甲基-3-烯-丁酸甲酯的合成研究
SYNTHESIS OF 2-MONOETHYL SUCCINYL-9,9-BIS(METHOXYMETHYL) FLUORENE
2-丁二酸單乙酯?；?9,9-雙甲氧甲基芴的合成
Synthesis of Cis and Trans 1,4 Dimethoxy 2 butene
順式和反式1,4-二甲氧基-2-丁烯的合成
Study on Isolation Process of 3-methyl-1-butene
3-甲基-1-丁烯的分離工藝研究